Potassium Adsorption Phenomenon in Calcareous Soils of Shahrazur Plain
https://doi.org/10.24017/science.2021.1.10
Abstract views: 1015 / PDF downloads: 647Abstract
A laboratory study for adsorption of potassium (K) determination was conducted on six soils located in Sharazur plain from the Kurdistan Region of Iraq in 2021 using the batch technique method. Potassium (K) adsorption isotherms were achieved by equilibrating 5.0 g of soil samples with eight grades of K (0 to 300 mg L-1) as KCl in 50 ml of 0.01M CaCl2 solution. To match the data of adsorption, Freundlich, Langmuir, and Temkin adsorption isotherms were used. The results show that the amount of adsorbed K ranged between (45.78 to 52.49) % added K. The Freundlich model fit the equilibrium K adsorption data better for the Serwan location of soil (silty loam), as demonstrated by a greater coefficient of determination (R2 =0.90). The value of heterogeneity factor 1/n for the Freundlich model ranged from (0.34 to 0.47) kg mg-1, which was less than one. The sorption processes for all of the studied soils were normal adsorption. The constant of the Langmuir isotherm (KL) aligned from (0.107 to o.425) L mg-1. Smaller KL values mean that more adsorbed K would be transformed to a non-exchangeable form, either through the creation of crystalline K or through ion occultation. The RL values indicate the type of isotherm, the values of RL> 1 that means the adsorption nature to be unfavorable. The Temkin equilibrium binding constant (AT) was high for all studied soils except the soils of Bestan Sur and Grdigo locations, the high value of AT indicates high binding energy. The Temkin constant (bT) ranged from (10.46 to 13.47) J mole-1 that was related to the nature of the adsorption energy, a positive value indicates that the adsorption process is exothermic.
Keywords:
Potassium adsorption, Freundlich model, Langmuir model, Temkin model.
References
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https://doi.org/10.9790/5736-0313845
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https://doi.org/10.1016/j.aca.2004.07.048
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https://doi.org/10.1016/j.jhazmat.2005.08.022
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https://doi.org/10.1002/app.1984.070290504
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https://doi.org/10.1080/00103620601094049
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https://doi.org/10.1016/S0008-6223(00)00128-7
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https://doi.org/10.1016/j.jhazmat.2005.10.016
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https://doi.org/10.1155/2013/208087
[37] K. D. Auge, T. M. Assefa, W. H. Woldeyohannes, and B. T. Asfaw, "Potassium adsorption characteristics of five different textured soils under enset (Ensete ventricosom cheesman) farming systems of Sidama zone, South Ethiopia," Journal of Soil Science and Environmental Management, vol. 9, pp. 1-12, 2018.
https://doi.org/10.5897/JSSEM2017.0666
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https://doi.org/10.1080/00103624.2018.1563097
[39] S. Mandzhieva, T. Minkina, D. Pinskiy, T. Bauer, and S. Sushkova, "The role of soil's particle-size fractions in the adsorption of heavy metals," Eurasian Journal of Soil Science, vol. 3, pp. 197-205, 2014.
https://doi.org/10.18393/ejss.16003
[40] O. Kenyanya, J. M. Wachira, and H. Mbuvi, "Determination of potassium levels in intensive subsistence agricultural soils in Nyamira County, Kenya," 2013.
[41] G. A. Mam Rasul, "Potassium adsorption in calcareous soils of Kurdistan region of Iraq," Iraqi Journal of Agricultural Sciences, vol. 51, 2020.
https://doi.org/10.36103/ijas.v51iSpecial.881
[42] A. A. Mehadi and R. W. Taylor, "Phosphate adsorption by two highly?weathered soils," Soil Science Society of America Journal, vol. 52, pp. 627-632, 1988.
https://doi.org/10.2136/sssaj1988.03615995005200030005x
[43] M. Del Bubba, C. Arias, and H. Brix, "Phosphorus adsorption maximum of sands for use as media in subsurface flow constructed reed beds as measured by the Langmuir isotherm," Water Research, vol. 37, pp. 3390-3400, 2003.
https://doi.org/10.1016/S0043-1354(03)00231-8
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https://doi.org/10.1016/S0045-6535(00)00121-1
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https://doi.org/10.2136/sssaj1956.03615995002000040007x
https://doi.org/10.1007/978-3-642-10613-2_9
[2] V. Römheld and G. Neumann, "The rhizosphere: contributions of the soil-root interface to sustainable soil systems," Biological approaches to sustainable soil systems, pp. 92-107, 2006.
https://doi.org/10.1201/9781420017113.ch7
[3] H. Zhang, M. Xu, W. Zhang, and X. He, "Factors affecting potassium fixation in seven soils under 15-year long-term fertilization," Chinese Science Bulletin, vol. 54, pp. 1773-1780, 2009.
https://doi.org/10.1007/s11434-009-0164-9
[4] M. Simonsson, S. Andersson, Y. Andrist-Rangel, S. Hillier, L. Mattsson, and I. Öborn, "Potassium release and fixation as a function of fertilizer application rate and soil parent material," Geoderma, vol. 140, pp.188-198, 2007.
https://doi.org/10.1016/j.geoderma.2007.04.002
[5] G. Rehm and M. Schmitt, "Potassium for crop production," Retrieved February, vol. 2, p. 2011, 2002.
[6] a. D. S. S. Shanwall A. V.,. "Potassium Dynamics and Mineralogy," Taylor and Francis, Encyclopedia of Soil Science, vol. 2, p. 4, 2006.
[7] Y. Du, S. Hayashi, and Y. Xu, "Some factors controlling the adsorption of potassium ions on clayey soils," Applied Clay Science, vol. 27, pp. 209-213, 2004.
https://doi.org/10.1016/j.clay.2004.06.003
[8] M. Jalali, "Kinetics of non-exchangeable potassium release and availability in some calcareous soils of western Iran," Geoderma, vol. 135, pp. 63-71, 2006.
https://doi.org/10.1016/j.geoderma.2005.11.006
[9] M. Simonsson, S. Hillier, and I. Öborn, "Changes in clay minerals and potassium fixation capacity as a result of release and fixation of potassium in long-term field experiments," Geoderma, vol. 151, pp. 109-120, 2009.
https://doi.org/10.1016/j.geoderma.2009.03.018
[10] M. Murashkina, R. Southard, and G. Pettygrove, "Potassium fixation in San Joaquin Valley soils derived from granitic and nongranitic alluvium," Soil Science Society of America Journal, vol. 71, pp. 125-132, 2007.
https://doi.org/10.2136/sssaj2006.0060
[11] R. Pannu, Y. Singh, B. Singh, and C. Khind, "Long term effects of organic materials on depth wise distribution of different K fractions in soil profile under rice-wheat cropping system," Journal of Potassium Research, vol. 18, pp. 1-5, 2002.
[12] N. Barrow, "The description of phosphate adsorption curves," Journal of Soil Science, vol. 29, pp. 447-462,1978.
https://doi.org/10.1111/j.1365-2389.1978.tb00794.x
[13] J. F. Porter, G. McKay, and K. Choy, "The prediction of sorption from a binary mixture of acidic dyes using single-and mixed-isotherm variants of the ideal adsorbed solute theory," Chemical Engineering Science, vol. 54, pp. 5863-5885, 1999.
https://doi.org/10.1016/S0009-2509(99)00178-5
[14] N. Atar, A. Olgun, and S. Wang, "Adsorption of cadmium (II) and zinc (II) on boron enrichment process waste in aqueous solutions: batch and fixed-bed system studies," Chemical Engineering Journal, vol. 192, pp. 1-7, 2012.
https://doi.org/10.1016/j.cej.2012.03.067
[15] G. W. Gee and D. Or, "2.4 Particle?size analysis," Methods of soil analysis: Part 4 physical methods, vol. 5, pp. 255-293, 2002.
https://doi.org/10.2136/sssabookser5.4.c12
[16] D. L. Suarez, "Beryllium, magnesium, calcium, strontium, and barium," Methods of Soil Analysis: Part 3 Chemical Methods, vol. 5, pp. 575-601, 1996.
https://doi.org/10.2136/sssabookser5.3.c20
[17] D. W. Nelson and L. E. Sommers, "Total carbon, organic carbon, and organic matter," Methods of Soil Analysis: Part 3 Chemical Methods, vol. 5, pp. 961-1010, 1996.
https://doi.org/10.2136/sssabookser5.3.c34
[18] G. Rayment and F. R. Higginson, Australian laboratory handbook of soil and water chemical methods: Inkata Press Pty Ltd, 1992.
[19] G. Drouineau, "Dosage rapide du calcaire actif du sol: Nouvelles données sur la separation et la nature des fractions calcaires," Ann. Agron, vol. 12, pp. 441-450, 1942.
[20] S. Mandal, T. Padhi, and R. Patel, "Studies on the removal of arsenic (III) from water by a novel hybrid material," Journal of hazardous materials, vol. 192, pp. 899-908, 2011.
https://doi.org/10.1016/j.jhazmat.2011.05.099
[21] B. M. Vanderborght and R. E. Van Grieken, "Enrichment of trace metals in water by adsorption on activated carbon," Analytical Chemistry, vol. 49, pp. 311-316, 1977.
https://doi.org/10.1021/ac50010a032
[22] K. Y. Foo and B. H. Hameed, "Insights into the modeling of adsorption isotherm systems," Chemical Engineering Journal, vol. 156, pp. 2-10, 2010.
https://doi.org/10.1016/j.cej.2009.09.013
[23] A. W. Adamson and A. P. Gast, Physical chemistry of surfaces vol. 15: Interscience publishers New York, 1967.
[24] E. Voudrias, K. Fytianos, and E. Bozani, "Sorption-desorption isotherms of dyes from aqueous solutions and wastewaters with different sorbent materials," Global Nest Int. J, vol. 4, pp. 75-83, 2002.
https://doi.org/10.30955/gnj.000233
[25] S. Puttamat and V. Pavarajarn, "Adsorption study for removal of Mn (II) ion in aqueous solution by hydrated ferric (III) oxides," International Journal of Chemical Engineering and Applications, vol. 7, pp. 239-243, 2016.
https://doi.org/10.18178/ijcea.2016.7.4.581
[26] A. Dada, A. Olalekan, A. Olatunya, and O. Dada, "Langmuir, Freundlich, Temkin and Dubinin- Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk," IOSR Journal of Applied Chemistry, vol. 3, pp. 38-45, 2012.
https://doi.org/10.9790/5736-0313845
[27] F. Rashidi, R. S. Sarabi, Z. Ghasemi, and A. Seif, "Kinetic, equilibrium and thermodynamic studies for the removal of lead (II) and copper (II) ions from aqueous solutions by nanocrystalline TiO2," Superlattices and microstructures, vol. 48, pp. 577-591, 2010.
https://doi.org/10.1016/j.spmi.2010.09.011
[28] G. T. Rushton, C. L. Karns, and K. D. Shimizu, "A critical examination of the use of the Freundlich isotherm in characterizing molecularly imprinted polymers (MIPs)," Analytica chimica acta, vol. 528, pp. 107-113, 2005.
https://doi.org/10.1016/j.aca.2004.07.048
[29] C. Namasivayam and R. Yamuna, "Waste biogas residual slurry as an adsorbent for the removal of Pb (II) from aqueous solution and radiator manufacturing industry wastewater," Bioresource Technology, vol. 52, pp. 125-131, 1995.
https://doi.org/10.1016/0960-8524(95)00006-Z
[30] K. V. Kumar and S. Sivanesan, "Isotherm parameters for basic dyes onto activated carbon: Comparison of linear and non-linear method," Journal of hazardous materials, vol. 129, pp. 147-150, 2006.
https://doi.org/10.1016/j.jhazmat.2005.08.022
[31] G. Mckay, H. Blair, and J. Gardner, "The adsorption of dyes onto chitin in fixed bed columns and batch adsorbers," Journal of Applied Polymer Science, vol. 29, pp. 1499-1514, 1984.
https://doi.org/10.1002/app.1984.070290504
[32] S. Khattri and M. Singh, "Adsorption of basic dyes from aqueous solution by natural adsorbent," 1999.
[33] A. Reyhanitabar, N. Karimian, M. Ardalan, G. Savaghebi, and M. Ghannadha, "Comparison of five adsorption isotherms for prediction of zinc retention in calcareous soils and the relationship of their coefficients with soil characteristics," Communications in soil science and plant analysis, vol. 38, pp. 147- 158, 2007.
https://doi.org/10.1080/00103620601094049
[34] G. O. Wood, "Affinity coefficients of the Polanyi/Dubinin adsorption isotherm equations: A review with compilations and correlations," Carbon, vol. 39, pp. 343-356, 2001.
https://doi.org/10.1016/S0008-6223(00)00128-7
[35] K. Vijayaraghavan, T. Padmesh, K. Palanivelu, and M. Velan, "Biosorption of nickel (II) ions onto Sargassum wightii: application of two-parameter and three-parameter isotherm models," Journal of hazardous materials, vol. 133, pp. 304-308, 2006.
https://doi.org/10.1016/j.jhazmat.2005.10.016
[36] N. A. Fathy, O. I. El-Shafey, and L. B. Khalil, "Effectiveness of alkali-acid treatment in enhancement the adsorption capacity for rice straw: the removal of methylene blue dye," International Scholarly Research Notices, vol. 2013, 2013.
https://doi.org/10.1155/2013/208087
[37] K. D. Auge, T. M. Assefa, W. H. Woldeyohannes, and B. T. Asfaw, "Potassium adsorption characteristics of five different textured soils under enset (Ensete ventricosom cheesman) farming systems of Sidama zone, South Ethiopia," Journal of Soil Science and Environmental Management, vol. 9, pp. 1-12, 2018.
https://doi.org/10.5897/JSSEM2017.0666
[38] M. Kassa, W. Haile, and F. Kebede, "Evaluation of adsorption isotherm models for potassium adsorption under different soil types in Wolaita of Southern Ethiopia," Communications in soil science and plant analysis, vol. 50, pp. 388-401, 2019.
https://doi.org/10.1080/00103624.2018.1563097
[39] S. Mandzhieva, T. Minkina, D. Pinskiy, T. Bauer, and S. Sushkova, "The role of soil's particle-size fractions in the adsorption of heavy metals," Eurasian Journal of Soil Science, vol. 3, pp. 197-205, 2014.
https://doi.org/10.18393/ejss.16003
[40] O. Kenyanya, J. M. Wachira, and H. Mbuvi, "Determination of potassium levels in intensive subsistence agricultural soils in Nyamira County, Kenya," 2013.
[41] G. A. Mam Rasul, "Potassium adsorption in calcareous soils of Kurdistan region of Iraq," Iraqi Journal of Agricultural Sciences, vol. 51, 2020.
https://doi.org/10.36103/ijas.v51iSpecial.881
[42] A. A. Mehadi and R. W. Taylor, "Phosphate adsorption by two highly?weathered soils," Soil Science Society of America Journal, vol. 52, pp. 627-632, 1988.
https://doi.org/10.2136/sssaj1988.03615995005200030005x
[43] M. Del Bubba, C. Arias, and H. Brix, "Phosphorus adsorption maximum of sands for use as media in subsurface flow constructed reed beds as measured by the Langmuir isotherm," Water Research, vol. 37, pp. 3390-3400, 2003.
https://doi.org/10.1016/S0043-1354(03)00231-8
[44] R. Anderson and Y. Wu, "Phosphorus quantity-intensity relationships and agronomic measures of P in surface layers of soil from a long-term slurry experiment," Chemosphere, vol. 42, pp. 161-170, 2001.
https://doi.org/10.1016/S0045-6535(00)00121-1
[45] O. Rehman, A. Ranjha, S. Saleem, and A. Khan, "Phosphorus requirement of wheat using modified Freundlich model in Sultanpur (Pakistan) soil series," Int. J. Agric. Biol, vol. 7, pp. 74-78, 2005.
[46] M. Fried and R. Shapiro, "Phosphate supply pattern of various soils," Soil Science Society of America Journal, vol. 20, pp. 471-475, 1956.
https://doi.org/10.2136/sssaj1956.03615995002000040007x
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How to Cite
[1]
K. S. Saeed, “Potassium Adsorption Phenomenon in Calcareous Soils of Shahrazur Plain”, KJAR, vol. 6, no. 1, pp. 95–109, Jul. 2021, doi: 10.24017/science.2021.1.10.
Published
07-07-2021
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Section
Pure and Applied Science
